| Date | Fixture | Result | Score | Competition |
|---|---|---|---|---|
| 23 Aug 1954 | Plymouth Argyle v Liverpool | L | 1-0 | League Division Two |
| 01 Sep 1954 | Liverpool v Plymouth Argyle | D | 3-3 | League Division Two |
| 01 Oct 1955 | Liverpool v Plymouth Argyle | W | 4-1 | League Division Two |
| 11 Feb 1956 | Plymouth Argyle v Liverpool | L | 4-0 | League Division Two |
| 26 Sep 1959 | Liverpool v Plymouth Argyle | W | 4-1 | League Division Two |
| 13 Feb 1960 | Plymouth Argyle v Liverpool | D | 1-1 | League Division Two |
| 05 Nov 1960 | Plymouth Argyle v Liverpool | W | 0-4 | League Division Two |
| 24 Mar 1961 | Liverpool v Plymouth Argyle | D | 1-1 | League Division Two |
| 09 Dec 1961 | Liverpool v Plymouth Argyle | W | 2-1 | League Division Two |
| 28 Apr 1962 | Plymouth Argyle v Liverpool | W | 2-3 | League Division Two |
| 08 Jan 2017 | Liverpool v Plymouth Argyle | D | 0-0 | FA Cup |
| 18 Jan 2017 | Plymouth Argyle v Liverpool | W | 0-1 | FA Cup |