| Date | Fixture | Result | Score | Competition |
|---|---|---|---|---|
| 11 Mar 1905 | Doncaster Rovers v Liverpool | W | 1-4 | League Division Two |
| 21 Apr 1905 | Liverpool v Doncaster Rovers | W | 1-0 | League Division Two |
| 21 Aug 1954 | Liverpool v Doncaster Rovers | W | 3-2 | League Division Two |
| 18 Dec 1954 | Doncaster Rovers v Liverpool | L | 4-1 | League Division Two |
| 30 Mar 1956 | Doncaster Rovers v Liverpool | L | 1-0 | League Division Two |
| 02 Apr 1956 | Liverpool v Doncaster Rovers | L | 1-2 | League Division Two |
| 08 Sep 1956 | Doncaster Rovers v Liverpool | D | 1-1 | League Division Two |
| 12 Jan 1957 | Liverpool v Doncaster Rovers | W | 2-1 | League Division Two |
| 05 Oct 1957 | Liverpool v Doncaster Rovers | W | 5-0 | League Division Two |
| 19 Feb 1958 | Doncaster Rovers v Liverpool | D | 1-1 | League Division Two |
| 04 Jan 1969 | Liverpool v Doncaster Rovers | W | 2-0 | FA Cup |
| 05 Jan 1974 | Liverpool v Doncaster Rovers | D | 2-2 | FA Cup |
| 08 Jan 1974 | Doncaster Rovers v Liverpool | W | 0-2 | FA Cup |