The Reds face Niko Kovac's side at the Allianz Arena for the second-leg of their Champions League last 16 tie as they look to progress to the quarter-finals.
Klopp, who had plenty of combinations to choose from for his midfield set-up, has opted for Jordan Henderson to start as the number six.
Liverpool: Alisson, Alexander-Arnold, Matip, Van Dijk, Robertson, Milner, Wijnaldum, Henderson, Mane, Salah, Firmino.
Substitutes: Mignolet, Fabinho, Lovren, Sturridge, Lallana, Shaqiri, Origi.
Bayern: Neuer, Rafinha, Sule, Hummels, Alaba, Thiago, Martínez, James Rodríguez, Gnabry, Lewandowski, Ribéry.
Substitutes: Ulreich, Boateng, Goretzka, Davies, Jeong, Coman, Sanches.