| Date | Fixture | Result | Score | Competition |
|---|---|---|---|---|
| 02 Feb 1895 | Barnsley v Liverpool | W | 1-2 | FA Cup |
| 11 Feb 1895 | Liverpool v Barnsley | W | 4-0 | FA Cup |
| 08 Oct 1904 | Barnsley v Liverpool | W | 0-2 | League Division Two |
| 26 Dec 1904 | Liverpool v Barnsley | W | 2-1 | League Division Two |
| 03 Feb 1906 | Liverpool v Barnsley | W | 1-0 | FA Cup |
| 10 Jan 1914 | Liverpool v Barnsley | D | 1-1 | FA Cup |
| 15 Jan 1914 | Barnsley v Liverpool | W | 0-1 | FA Cup |
| 25 Dec 1945 | Liverpool v Barnsley | W | 5-2 | North Region War League |
| 26 Dec 1945 | Barnsley v Liverpool | L | 1-0 | North Region War League |
| 10 Dec 1955 | Liverpool v Barnsley | D | 1-1 | League Division Two |
| 10 Mar 1956 | Barnsley v Liverpool | W | 0-5 | League Division Two |
| 27 Oct 1956 | Barnsley v Liverpool | L | 4-1 | League Division Two |
| 09 Mar 1957 | Liverpool v Barnsley | W | 2-1 | League Division Two |
| 14 Dec 1957 | Barnsley v Liverpool | L | 2-1 | League Division Two |
| 26 Apr 1958 | Liverpool v Barnsley | D | 1-1 | League Division Two |
| 27 Mar 1959 | Liverpool v Barnsley | W | 3-2 | League Division Two |
| 30 Mar 1959 | Barnsley v Liverpool | W | 0-2 | League Division Two |
| 12 Jan 1982 | Liverpool v Barnsley | D | 0-0 | League Cup |
| 19 Jan 1982 | Barnsley v Liverpool | W | 1-3 | League Cup |
| 10 Mar 1985 | Barnsley v Liverpool | W | 0-4 | FA Cup |
| 22 Nov 1997 | Liverpool v Barnsley | L | 0-1 | Premier League |
| 28 Mar 1998 | Barnsley v Liverpool | W | 2-3 | Premier League |
| 16 Feb 2008 | Liverpool v Barnsley | L | 1-2 | FA Cup |
| 12 Jan 2026 | Liverpool v Barnsley | W | 4-1 | FA Cup |