The Reds can secure qualification with a 1-0 win over the Italian side, or if the visitors score, they must win by a clear two-goal margin.
All that goes out the window should Red Star manage to defeat PSG at home, with the Reds then only needing a victory of any kind to gain progression.
It promises to be yet another famous European night under the lights at Anfield and you can keep up with all the latest drama right here.
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Watch: Liverpool vs Napoli