The Reds will be hoping they can get a positive result to take to the Allianz Arena next month as they look to secure qualification to the quarter-finals.
Liverpool were last in action against Bournemouth ten days ago and the manager has made two changes to his side from that day.
Henderson joins Gini Wijnaldum and Naby Keita in midfield, with the latter getting the nod over Milner in the middle of the park.
Liverpool: Alisson, Alexander-Arnold, Matip, Fabinho, Robertson, Henderson, Wijnaldum, Keita, Salah, Firmino, Mane.
Substitutes: Moreno, Milner, Lallana, Shaqiri, Origi, Sturridge.
Bayern Munich: Neuer, Kimmich, Sule, Hummels, Alaba, Martinez, Thiago, Gnabry, James, Coman, Lewandowski.
Substitutes: Ulreich, Rafinha, Ribéry, Davies, Mai, Sanches, Shabani.